Coach: Alejandro Sabella

The final squad announced on 2 June 2014:[43][44]

No.Pos.PlayerDoB/AgeCapsClub
1GKSergio Romero22 February 1987 (aged 27)47France AS Monaco
2DFEzequiel Garay10 October 1986 (aged 27)18Portugal Benfica
3DFHugo Campagnaro27 June 1980 (aged 33)15Italy Internazionale
4DFPablo Zabaleta16 January 1985 (aged 29)36England Manchester City
5MFFernando Gago10 April 1986 (aged 28)49Argentina Boca Juniors
6MFLucas Biglia30 January 1986 (aged 28)18Italy Lazio
7MFÁngel di María14 February 1988 (aged 26)47Spain Real Madrid
8MFEnzo Pérez22 February 1986 (aged 28)7Portugal Benfica
9FWGonzalo Higuaín10 December 1987 (aged 26)36Italy Napoli
10FWLionel Messi (c)24 June 1987 (aged 26)86Spain Barcelona
11MFMaxi Rodríguez2 January 1981 (aged 33)55Argentina Newell's Old Boys
12GKAgustín Orión26 July 1981 (aged 32)3Argentina Boca Juniors
13MFAugusto Fernández10 April 1986 (aged 28)9Spain Celta Vigo
14MFJavier Mascherano8 June 1984 (aged 30)98Spain Barcelona
15DFMartín Demichelis20 December 1980 (aged 33)38England Manchester City
16DFMarcos Rojo20 March 1990 (aged 24)22Portugal Sporting
17DFFederico Fernández21 February 1989 (aged 25)26Italy Napoli
18FWRodrigo Palacio5 February 1982 (aged 32)22Italy Internazionale
19MFRicardo Álvarez12 April 1988 (aged 26)7Italy Internazionale
20FWSergio Agüero2 June 1988 (aged 26)51England Manchester City
21GKMariano Andújar30 July 1983 (aged 30)10Italy Catania
22FWEzequiel Lavezzi3 May 1985 (aged 29)31France Paris Saint-Germain
23DFJosé María Basanta3 April 1984 (aged 30)10Mexico Monterrey