Coach: Argentina Jorge Sampaoli

The final squad announced on 1 June 2014:[12]

No.Pos.PlayerDoB/AgeCapsClub
1GKClaudio Bravo (c)13 April 1983 (aged 31)79Spain Real Sociedad
2DFEugenio Mena18 July 1988 (aged 25)24Brazil Santos
3DFMiiko Albornoz3 November 1990 (aged 23)2Sweden Malmö FF
4MFMauricio Isla12 June 1988 (aged 26)46Italy Juventus
5MFFrancisco Silva11 February 1986 (aged 28)11Spain Osasuna
6MFCarlos Carmona21 February 1987 (aged 27)43Italy Atalanta
7FWAlexis Sánchez19 December 1988 (aged 25)66Spain Barcelona
8MFArturo Vidal22 May 1987 (aged 27)53Italy Juventus
9FWMauricio Pinilla4 February 1984 (aged 30)26Italy Cagliari
10MFJorge Valdívia3 October 1983 (aged 30)56Brazil Palmeiras
11FWEduardo Vargas20 November 1989 (aged 24)29Spain Valencia
12GKCristopher Toselli22 June 1988 (aged 25)4Chile Universidad Católica
13DFJosé Rojas3 June 1983 (aged 31)18Chile Universidad de Chile
14MFFabián Orellana27 January 1986 (aged 28)25Spain Celta Vigo
15MFJean Beausejour3 June 1984 (aged 30)59England Wigan Athletic
16MFFelipe Gutiérrez8 October 1990 (aged 23)17Netherlands Twente
17DFGary Medel3 August 1987 (aged 26)60Wales Cardiff City
18DFGonzalo Jara29 August 1985 (aged 28)65England Nottingham Forest
19MFJosé Pedro Fuenzalida22 February 1985 (aged 29)23Chile Colo-Colo
20MFCharles Aránguiz17 April 1989 (aged 25)20Brazil Internacional
21MFMarcelo Díaz30 December 1986 (aged 27)20Switzerland Basel
22FWEsteban Paredes1 August 1980 (aged 33)34Chile Colo-Colo
23GKJohnny Herrera9 May 1981 (aged 33)7Chile Universidad de Chile